INTRODUCTION |
Since several years, large efforts are made in the blast furnace field to increase the substitution of coke by |
coal in order to meet changing economical and environmental conditions. The experience gained until now |
shows that the increase of PCI rate induces important changes of gas distribution in the blast furnace which |
influence the whole process, the performance and the service life. Gas flow monitoring is therefore regarded |
as one of the keys to high PCI rates. |
Gas distribution being the result of numerous interacting phenomena, the best approach consists in |
establishing a mathematical model of the gas flow inside the blast furnace. |
DESCRIPTION OF THE BLAST FURNACE MODEL |
Basic principles |
The blast furnace is modelled in a steady state. Therefore, it is assumed to be charged and emptied |
continuously. The liquid level is considered as horizontal and fixed ; however, it is a parameter. The layered |
structure is assumed to be fixed, which is allowed by the fact that the gas velocity is much higher than the |
solids velocity. |
Assuming an axial symmetry, the model is bi-dimensional and written in cylindrical co-ordinates. The |
system of differential equations is solved by the finite differences method. |
The input data are : the blast furnace geometry, the process data (blast conditioning, coal injection rate, top |
pressure, etc.), the chemical and physical properties of the raw materials, the chemical composition of hot |
metal and slag and the complete description of ore and coke layers (thickness and grain size distribution |
along the radius). |
The model simulates the burden distribution inside the whole blast furnace, the gas flow through the layered |
structure, the solids flow, the liquids flow, the heat transfer between the different phases and with the walls, |
the ore softening and melting in the cohesive zone as well as the main chemical reactions. |
The work has been restricted to the main phenomena of the blast furnace. Some sub-models like liquids flow |
and softening-melting have been simplified ; the phenomena taking place in the raceway have been limited |
to a classical heat and mass balance. Attempts were made to include a char transportation and consumption |
sub-model, but it was finally concluded that a research project completely devoted to this problem would be |
necessary to approach a valuable solution. |
The general architecture of the model is shown at |
figure 1. |
The modular structure makes the model more |
understandable, allowing easy modifications and |
further improvements. But, due to the interactions |
between the blast furnace phenomena, the different |
modules are integrated into a complex looping |
procedure. |
The results of the model consist in a complete |
description of each point of the blast furnace, i.e. the |
fields of temperature, pressure, velocity and chemical |
composition of gas, solids and liquids, as well as the |
wall thermal losses distribution. |
Geometry |
The model has been applied to the geometry and the |
operating conditions of the blast furnace B of Sidmar. |
The bottom of the calculation field corresponds to the |
liquid surface which is assumed to be fixed and |
horizontal. The raceway and the dead man shapes have |
been fixed according to relevant literature. |
The blast furnace must be divided into a great number of cells in order to obtain a correct description of the |
phenomena like the gas flow through the layers of materials. A compromise between the calculation time |
and the quality of the results led to a grid of 20 x 120 cells. For a blast furnace of 10.5 m in hearth diameter, |
the mesh dimension is then 0.30 m x 0.23 m. On a Digital Personal Workstation 433 AU, the computation |
time amounts generally to 3 hours. This time depends highly on the degree of severity imposed for |
convergence detection. This model working off line, such a high computation time is not really a dramatic |
drawback. Moreover, it could still be improved by using more rapid calculators. The program is written in |
FORTRAN. |
Burdening model |
Most plants already calculate the ore and coke layers geometry at the top with their own burden distribution |
model adapted to their individual situation. The modular conception of the present model allows a perfect |
integration of these existing auxiliary models. In the present work, we use the Sidmar burdening model [1] |
which applies to a bell-less top. This model calculates the layers thickness as well as the grain size |
distribution along the blast furnace radius. It calculates also the radial distribution of the resistance to gas |
flow resulting from the Ergun's law. |
The Sidmar burdening model (figure 2) takes into account the trajectory of each type of material for each |
position of the chute, the thickness of the material flow, the dynamic effects generated at the impact point of |
the materials on the burden surface, the grain size segregation (at the hoppers discharge, on the chute and on |
the burden surface) and the percolation. The results are in good agreement with the microwave profilometer |
measurements [2]. |
The structure and the properties of the layers are then |
extended from the top to the bottom of the blast furnace |
on the basis of the results of the solid flow sub-model |
explained below. |
Gas flow |
This sub-model calculates the gas velocity and pressure |
at any point of the blast furnace, being given the gas flow |
rate at tuyeres, the top pressure, the blast furnace |
geometry and the layered structure of the burden. |
In the dry zone, the voidage of each material is a |
function of height and radial position. The values are |
based on measurements [3] made on samples issued from |
the Mannesmann furnace quenched with nitrogen in |
1981. In the cohesive zone and in the dripping zone, the |
voidage has been decreased to take into account the |
volume occupied by the liquids. |
The Ergun equation [4] which holds in a homogeneous |
field, can be written in a vectorial form : |
P |
= |
- |
( |
+ |
. |
| |
G |
| |
) |
G |
f |
f |
1 |
2 |
G |
gas flow vector, reported to the empty reactor section [kg/m |
.s] |
2 |
P static pressure [Pa] |
f |
laminar flow resistance factor [s |
] |
-1 |
1 |
f |
turbulent flow resistance factor [m |
/kg] |
2 |
2 |
The mass conservation of gas is described by : |
. |
( |
G |
/M) = Cr_Gas |
M molecular weight of the gas [kg/kmol] |
Cr_Gas rate of gas creation by chemical reactions |
(carbon gasification by CO |
and H |
O) |
2 |
2 |
[kmol/m |
.s] |
3 |
A preliminary study of the different resolution methods |
allowed to select the Direct Differential Method |
because it gives the best precision together with one of |
the shortest calculation times. |
Figure 3 shows the calculated gas velocity field at the |
entrance of the cohesive zone. It can be seen that the |
gas velocities are greater in the coke layers than in the |
ore layers. Moreover, to cross the cohesive zone, the |
gas tries to avoid the softening and melting ores by |
flowing mainly through the coke "windows" ; the small |
part of the gas which passes through the less permeable |
ore layers follows a path as short as possible i.e. almost |
perpendicular to the interfaces. |
Solids and liquids flows |
The determination of the solids flow is based on is based on a potential model taking into account the |
vanishing of solids by melting and by gasification. The main hypotheses are the following : |
- imposed dead man, |
- uniform distribution of solids velocity at the blast furnace |
top, |
- the burning rate of coke in the raceway does not depend on |
the radius. |
The basic mass conservation equation is written as follows : |
S |
( |
) |
= |
- |
Gasif |
- |
Melt |
- |
Burn |
t |
• |
b |
S |
solids flow vector [kg/m |
.s] |
2 |
solids bulk density [kg/m |
] |
3 |
b |
Gasif carbon gasification reaction rate by CO |
and H |
O |
2 |
2 |
[m |
/m |
.s] |
3 |
3 |
Melt ore melting rate [m |
/m |
.s] |
3 |
3 |
Burnt coke burnt in the raceway [m |
/m |
.s] |
3 |
3 |
The solution is obtained through the introduction of a potential |
function |
[m |
/s] such that : |
2 |
v |
= |
- |
k |
v solids velocity [m/s] |
k resistance to gas flow [-] |
The potential function is set at 0 on the raceway section. This |
elliptic problem is solved by the over-relaxation method. |
Figure 4 shows an example of results. The layer thickness |
decreases progressively from the top to the tuyeres. In the upper part of the bosh, the coke layers have an |
average thickness of 0.08 m at the wall which can be |
compared to 0.21 m observed at the top. The inclination |
angle of the layers decreases also : from 30° at the top, it |
reaches about 6° in the belly. From the start of melting |
line to the end of melting line, the ore layers become |
thinner and thinner which reflects the melting |
phenomenon. |
These results fit very well with the observations made on |
several dissected blast furnaces, as for example on |
Hirohata n°1 BF of Nippon Steel (figure 5) [5]. This |
figure highlights also a sharp inverted V shape cohesive |
zone with a very low root touching the wall and the |
raceway as in the model results. In the belly, the model |
calculates cohesive rings of 1.7 m width which can be |
compared to values ranging from 1.2 to 1.7 m on figure 5. |
As concerns the liquids issued from the melting line, they |
are supposed to flow vertically into the hearth. |
Heat transfer |
The main supplementary data required for the heat transfer description are the temperature of the gas issued |
from the raceway and the standard heats of the chemical reactions. At steady state, the conservation of |
energy and the thermal transfers between the solids, liquids and gas phases are described by : |
For liquids : - |
. (H |
. |
G |
) + |
. (k |
T |
) - Q |
+ S a |
. R |
. H |
= 0 |
l |
l |
l |
l |
tr, l |
l, i |
i |
r, i |
For gas : - |
. (H |
. |
G |
) + |
. (k |
T |
) - Q |
+ S a |
. R |
. H |
= 0 |
g |
g |
g |
g |
tr, g |
g, i |
i |
r, i |
For solids : - |
. (H |
. |
G |
) + |
. (k |
T |
) - Q |
+ S a |
. R |
. H |
= 0 |
s |
s |
s |
s |
tr, s |
s, i |
i |
r, i |
with, for each phase, |
H enthalpy at temperature T [J/kg] |
G |
mass flow vector, reported to the empty reactor section [kg/m |
.s] |
2 |
k thermal conductivity [J/m.EC] |
T temperature [°C] |
Q |
heat transferred to the other phases and to the cooling medium by convection and radiation [W/s] |
tr |
R |
rate of reaction i [kmol/m |
.s] |
3 |
i |
H |
heat of reaction i [J/kmol] |
r, i |
a |
proportion of the heat of reaction i absorbed by the considered phase [-] |
i |
The heat transferred by the liquids by conduction and radiation as well as the heat transferred by radiation by |
the gas have been neglected. |
The Kitaiev correlations [6] have been chosen to quantify the heat transfer coefficient between gas and |
solids and to account for heat conduction inside the solid particles. However, like many authors, we have |
applied a correction factor to the heat transfer coefficient at temperatures higher than 1000°C. |
The heat transfer coefficients gas-liquids and solids-liquids have been determined by calibration on |
industrial data in order to produce hot metal and slag at the right temperature. |
The boundary conditions are expressed by the wall temperatures, themselves calculated by the following |
heat transfer equation : |
h |
. |
( |
- |
) |
= |
h |
. |
( |
- |
) |
T |
T |
T |
T |
p |
w |
wat |
w |
g |
w |
h |
global heat transfer coefficient wall-cooling water [W/m |
.°C] |
2 |
p |
h |
global convection and conduction heat transfer coefficient granular bed-wall (W/m |
.°C) |
2 |
w |
T |
cooling water temperature (°C) |
wat |
T |
gas temperature at the wall (°C) |
g |
T |
wall surface temperature (°C) |
w |
The global heat transfer coefficient wall-cooling water has been determined in function of the height by |
calibration on industrial data from BF B of Sidmar. The coefficient h |
is calculated following the method set |
w |
up by Yagi and Kunii [7]. |
Cohesive zone sub-model |
The cohesive zone starts where the solids reach 1200°C and ends where the ore is completely melted. The |
ore melting degree is calculated from the available heat resulting of heat transfer. It is calculated by means |
of an under-relaxation procedure which continues until convergence i.e. until the assumed and calculated |
vertical positions of both isotherms don't differ more than a half mesh, which means about 0.12 m in height. |
Chemical reactions sub-model |
The model considers the following reactions : |
Fe |
O |
+ CO = Fe |
O |
+ CO |
(reaction 1) |
x |
y |
x |
y-1 |
2 |
CO |
+ C = 2 CO |
(reaction 2) |
2 |
Fe |
O |
+ H |
= Fe |
O |
+ H |
O (reaction 3) |
x |
y |
2 |
x |
y-1 |
2 |
C + H |
O = CO + H |
(reaction 4) |
2 |
2 |
CO + H |
O = CO |
+ H |
(reaction 5) |
2 |
2 |
2 |
The gas composition and flow rate are known at the tuyere tip. It is supposed that in a given cell the |
chemical reactions develop without any interference and that no diffusion of chemical species occur from |
one cell to the others. Iron and slag are supposed to reach their final composition as soon as they are formed |
in the cohesive zone. |
In each cell, and for each chemical species, the continuity equation is expressed by |
. |
( |
F |
) = R |
i |
i |
F |
flux vector of the i species expressed on the empty section of the reactor [kmol/m |
.s] |
2 |
i |
R |
difference between generation and consumption rates of the i species [kmol/m |
.s]. |
3 |
i |
A single stage reduction model applied to porous spherical particles is used [8, 9]. The reactions are of first |
order relative to the partial pressures of the gas components. The diffusion inside the particles is considered |
but the diffusion through the boundary layer outside the particles is neglected, as it is of minor importance. |
Various expressions of the reaction rate constant can be found in literature. We adopted the following value |
[m/h] which is based on reduction tests performed in the 80 |
in CRM laboratory : |
ies |
k = 475 . exp [ - 10000 / ( 1.987 . T)] |
The value was obtained from the application of the preceding equations to experimental results. The |
equilibrium is calculated according to the results of Darken and Gurry [10]. |
For coke gasification by CO |
, a gasification model applied to porous spherical particles is used [9]. The |
2 |
reaction rates are of first order relative to the partial pressures of CO |
and CO. The diffusion of gas through |
2 |
the external boundary layer as well as through the pores of coke is taken into account. |
We use the reaction |
rate constant determined by Heynert [11]. |
The kinetics of reaction 4 is assumed proportional to the kinetics of reaction 2. Reaction 5 is assumed at |
equilibrium above 850°C ; below this temperature, it is neglected. |
CALIBRATION OF THE MODEL AND ILLUSTRATION OF THE RESULTS |
The calibration of the model is based on experimental data obtained by vertical probings and by gas tracing |
at blast furnace B of Sidmar. The results are illustrated below. |
The burden consisted of 88 % sinter and 12 % pellets. The coke rate was 287 kg/thm (including 27 kg/thm |
of nut coke charged together with sinter) with a coal rate of 178 kg/thm. The production level was 65 |
thm/m |
.day or 2.7 thm/m |
.day. |
2 |
3 |
The measured and calculated temperature profiles are reported at figures 6 and 7. The long thermal reserve |
zone observed on probes 1 to 4 is reproduced by the calculations but some tuning is still necessary to |
improve the fitting. The drying of solids shown by probe 1 below 5 m needs also to be improved in the |
simulation. Between 1000°C and 1300°C, area of reactions 2 and 4, the patterns of calculated temperature |
profiles are similar to those measured. Results concerning probes 5 and 6 can be regarded as good. |
Experimental and calculated results concerning the progress of chemical reactions are compared on a |
Chaudron diagram at figures 8 and 9. On both figures, the gas path shows a similar behaviour which leads to |
the conclusion that the chemical phenomena are fairly well simulated. |
The calculated radial profiles of top gas |
composition and temperature are also in good |
agreement with the measured ones, as can be |
seen at figure 10. |
At figure 11, the pressure profiles calculated |
along the wall compare well to the pressure |
profiles measured during the vertical probings |
both by the wall probe and by the wall pressure |
tappings. A pressure loss of 0.300 bar has been |
substracted from the pressure measured in the |
hot blast main to obtain the experimental value |
of the pressure at tuyere nose. |
Transfer times of gas from the tuyeres to the top are measured on blast furnace B of Sidmar by gas tracing |
with helium [12]. These measurements can also be used to calibrate the model. Figure 12 compares the |
experimental measurements to the results of the model. Despite small differences attributed to a systematic |
error in the measurement of gas transfer time through the sampling line, the profiles are almost parallel, |
indicating that the gas distribution in the blast furnace is correctly simulated. This result is worth to be |
highlighted, as gas distribution is the main objective of the present model. |
These comparisons lead to the conclusion that the mathematical model simulates correctly the main |
phenomena involved in the blast furnace process. |
SIMULATION OF THE INFLUENCE OF THE BURDEN DISTRIBUTION PATTERN |
The charging procedure being the most important means to influence the gas distribution, we selected by |
means of the Sidmar burdening model three typical charging procedures promoting without any doubt a |
central, a peripheral and an intermediate gas distribution. The layers configurations resulting from the |
Sidmar burdening model appear at the top of figure 13, as well as the radial distribution of the coke volumic |
fraction and of the resistance to gas flow. |
With charging pattern n°1, the coke volumic fraction reaches 100 % at the blast furnace center and only |
22 % at the wall ; as a consequence, the resistance to gas is very low at the center and relatively high at the |
wall. With charging pattern n° 2, coke and ore are distributed in such a way to obtain a uniform distribution |
of the resistance to gas flow. It is interesting to observe that the coke proportion is higher at the wall than at |
the centre because it is necessary to compensate for the grain size segregation effect. Charging pattern n° 3 |
has been designed to create a low resistance zone at the furnace periphery ; at the wall, the coke proportion |
reaches 54 %. |
The operation data have been described in the preceding chapter. In order to highlight the influence of the |
burden distribution, all the parameters of the model are kept constant for the three simulations. |
Figure 13 shows the gas temperature map and the calculated cohesive zone in the three cases. These results |
are in good agreement with industrial experience. It is also worth mentioning that the cohesive zone is much |
thinner with charging pattern n° 1. |
In the dry zone, the three pressure profiles are almost superposed, but they differ greatly in the cohesive and |
dripping zones. The calculated pressure drops are respectively 0.99 bar, 2.19 bar and 1.38 bar for the |
charging patterns n° 1, 2 and 3. Such a classification agrees well with experience. |
In practice, the characteristic curve of the blower will |
impose the operating conditions, so that charging |
patterns n° 2 and 3 will result into lower blast and |
production rates. To obtain a pressure loss of 0.99 bar in |
the three cases, the model calculates that the |
productivity will be respectively 64.8, 46.1 and 52.6 |
thm/m |
.day (i.e. 100 %, 71 % and 81 %). |
2 |
At figure 14, the three radial profiles of top gas |
temperature are compared. They fully agree to what |
might be expected. With charging pattern n° 1, the high |
temperatures observed at the centre allow to purge by the |
top a significative fraction of the alkalies load, as already |
reported industrially [13]. |
The radial profiles of top gas oxidation degree (figure15) |
are coherent with the top temperature profiles. The |
average value of the top gas CO2/(CO+CO2) ratio is |
respectively of 0.488, 0.525 and 0.527 for the charging |
types n° 1, 2 and 3. |
The profiles of heat losses through the walls highlight |
also the great differences between the three charging |
patterns that are mainly due to the different wall |
temperature profiles. As expected, the heat losses are lower with the |
n°1 charging pattern. After integration on the whole wall surface, heat |
losses of respectively 141 MJ/thm, 197 MJ/thm and 212 MJ/thm are |
calculated for cases n° 1 to 3 (i.e. 9130 kW, 12780 kW and |
13760 kW). |
The main results of these calculations are summarized in table I. |
The three typical charging patterns applied here above result in |
extremely different blast furnace operations. But much smaller |
charging modifications, more frequently encountered in the industrial |
practice, can also result in appreciable modifications of the blast |
furnace inner state and performance (figure 16). In this respect, the |
model can certainly help the operator to choose the most appropriate |
burden distribution pattern in function of the desired effect on the |
blast furnace results. |
Table I – Calculated results relative to the three charging types. |
Charging type |
Unit |
1 2 3 |
Pressure loss |
0.99 2.19 1.38 |
bar |
thm/m |
.24 h |
64.8 |
46.1 |
52.6 |
2 |
Productivity for a pressure loss of 0.99 bar |
% |
100 |
71 |
81 |
MJ/tHM |
141 |
195 |
212 |
Heat losses through the walls |
kW |
9130 |
12780 |
13760 |
Top gas CO |
/ (CO + CO |
) |
- |
0.488 0.525 0.527 |
2 |
2 |
Top gas temperature at BF centre |
818 161 46 |
°C |
SIMULATION OF THE INFLUENCE OF THE PRODUCTION RATE |
The influence of the production rate on the blast furnace performance has been simulated for two different |
charging patterns, one leading to a central operation and one leading to a uniform operation. Figures 17 and |
18 illustrate the effects observed on the cohesive zone. |
DISCUSSION OF THE RESULTS |
The model results show that the gas flow pattern and the cohesive zone are mainly dictated by the burden |
distribution. |
The change of gas distribution from the lower shaft to |
the upper shaft level is illustrated on figure 19 where the |
gas flow rates on both sections have been related to a |
normalized section divided into 10 rings of equal area. |
The change of gas distribution implies that some gas is |
moving from the central region towards the wall but the |
phenomenon is rather limited. Considering that, in the |
present simulation, the central part of the furnace is |
occupied by coke only, the gas distribution in the upper |
shaft appears very flat as the fraction of gas passing |
through the rings varies only in the range of 13 % to |
9 %. This result is totally different from the common |
feeling of a very high gas flow rate at the centre, feeling |
based on the usually measured top gas temperature |
profiles. In conclusion, the temperature profile is mainly |
related to the gas velocity profile but gives a poor |
indication on the gas flow rate profile. |
The validity field of the model could be enlarged by the modelling of other phenomena such as the |
behaviour of unburnt coal particles, voidage modifications, grain size alteration, channelling, accretion, |
scaffolding and peeling. As it includes the main phenomena involved in the blast furnace process and their |
interrelations, the present model is an appropriate frame to the development of such additional modelling |
work. |
CONCLUSIONS |
A mathematical model has been developed which simulates the main phenomena involved in the blast |
furnace process at steady state. It has been calibrated with experimental data obtained by vertical probings |
and by gas tracing at blast furnace B of Sidmar. |
The model results show the strong influence of the burden distribution pattern on the gas distribution and on |
the different operating results such as the pressure drop, the productivity, the shape and position of the |
cohesive zone, the top gas temperature profile and the heat losses through the wall. As a consequence, it can |
be used to simulate and to forecast the influence of the burden distribution changes which are made by the |
operator. Therefore, it is a powerful tool to help him to choose the proper burden distribution pattern in |
function of the desired effect on the blast furnace results. |
Sidmar has decided to implement the model for an industrial use. |
ACKNOWLEDGEMENTS |
This research has been carried out with financial support from the Belgian Public Authorities and from the |
ECSC. |
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